الرئيسية » أرشيف الوسم : rearrangement

أرشيف الوسم : rearrangement

backbiting

A rearrangement that can occur in some polymerization reactions involving free radicals. A radical that has an unpaired electron at the end of the chain changes into a radical with the unpaired electron elsewhere along the chain, the new radical being more stable than the one from which it originates. For ex­ample, the radical RCH2CH2CH2CH2CH2CH2·  may change into RCH2CH·CH2CH2CH2CH3 The rearrangement …

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